The
recommended storage temperature for most laptop batteries is 15°C (59°F); the
extreme allowable temperature is –40°C to 50°C (–40°C to 122°F) for most
chemistries. While lead acid must always be kept at full charge during
storage, nickel- and lithium-based chemistries should be stored at
around a 40 percent state-of-charge (SoC). This level minimizes
age-related capacity loss while keeping the battery in operating
condition and allowing self-discharge.
Finding
the 40 percent SoC level is difficult because the open circuit voltage
(OCV) of batteries does not lend itself well to state-of-charge
estimations. For lack of better methods, voltage is nevertheless used as
a rough fuel gauge indicator. The SoC of Li-ion is roughly 50 percent
at 3.80V/cell and 40 percent at 3.75V/cell. Allow Li-ion to rest 90
minutes after charge or discharge before taking the voltage reading to
get equilibrium.
SoC
on nickel-based batteries is especially difficult to measure. A flat
discharge curve, agitation after charge and discharge, and voltage
change on temperature contribute to the fluctuations. Since no other
estimation tool exists that is practical, and the charge level for
storage is not all too critical for this chemistry, simply apply some
charge if the battery is empty, and then make sure that the battery is
kept in a cool and dry storage.
Storage will always cause batteries to age. Low temperature and partial SoC only slow the effect. Table 1 illustrates the recoverable capacity
of lithium- and nickel-based batteries at various temperatures and
charge levels over one year. The recovered capacity is defined as the
available battery capacity after storage with a full charge.
You
can store a sealed lead acid battery for up to two years. Since all
batteries gradually self-discharge over time, it is important to check
the voltage and/or specific gravity, and then apply a charge when the
battery falls to 70 percent state-of-charge. This is typically the case
at 2.07V/cell or 12.42V for a 12V pack. (The specific gravity at 70
percent charge is roughly 1.218.) Some lead acid batteries may have
different readings and it is best to check the manufacturer’s
instruction manual. Low charge induces sulfation, an oxidation layer on
the negative plate that inhibits current flow. Topping charge and/or
cycling may restore some of the capacity losses in the early stages of
sulfation.
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